主编陈正华：毕业于南开大学化学系，硕士学位，副教授，是天津医科大学第一批授予留学生教学资格的教师。1995年至今在天津医科大学从事医用化学本科生、留学生教学。从事留学生英文授课17年。主持国家“十五”重点立项课题“21世纪中国高等学校农林/医药类专业数理化基础课程的创新与实践”子项目 ，医学化学（基础化学、有机化学融为一体）新课程体系的创新与研究”，主持天津医科大学教学研究基金“医用基础化学双语教学课程建设”，参与卫生部课题---视听教材医用化学综合性实验。主编供留学生使用的教材《GENERAL CHEMISTRY》，《Guid to Chemical Experiments》，《Experimental Organic Chemistry Fo rMedical Students》，校内出版。主持编写教育部全英文临床医学专业《基础化学英语教学大纲》。参编教育科学“十五”国家规划课题研究成果《医用化学实验》 高等教育出版社，《基础化学习题解析》 高等教育出版社， 《医用基础化学实验》 科学普及出版社。
目录
Chapter 1 Introduction 1
11 Chemistry is a Central Science 1
12 The Scope of the Book 1
13 Advice for Studying Chemistry 2
Chapter 2 Colligative Properties of Dilute Solutions 3
21 Concentration Expressions 3
22 Lowering of Vapor Pressure and RAOULT’S Law 4
23 Boiling Point Elevation 6
24 Freezing Point Depression 7
25 Osmotic Pressure 8 Exercises 12
Chapter 3 Acid-Base Dissociation Equilibria 13
31 Br?nsted-Lowry Theory of Acids and Bases13
32 The Autoionization of Water and the pH Scale 15
33 Ionization Constants for Weak Acids and Bases 16
34 Calculating the pH of Solutions of Weak Acids and Bases 20 Problems 25
Chapter 4 Buffer Solutions 26
41 Composition and Action of Buffer solutions 26
42 The pH Value of Buffer Solutions 27
43 Buffer Capacity and Buffer Range29
44 Preparation of Buffer Solutions 30
45 Buffer Solutions in Human Blood 32 Problems 33
Chapter 5 Acid-Base Titration 35
Introduction 35
51
52 Acid-Base Indicators 35
53 The Titration Curve and the Selection of Indicators 37
54 Standard Solutions of Acids and Bases 41
55 Application of Acid-Base Titration 43 Problems 44
Chapter 6 Thermodynamics 45
61 The First Law of Thermodynamics 45
62 Thermochemistry 48
63 The Second Law of Thermodynamics 52
64 Molar Gibbs Free Energy of Reaction 54 Problems 57
Chapter 7 Chemical Kinetics 59
71 The Rate of a Chemical Reaction 59
72 The Theory of Chemical Kinetics 60
73 Effect of Concentration on Rates of Reactions 61
74 Effect of Temperature on Reaction Rates 65 Problems 66
Chapter 8 Chemical Equilibrium 67
81 The Concept of Equilibrium 67
82 Equilibrium Constants 67
83 Calculating Values of Equilibrium Constants 68
84 Application of Equilibrium Constants 68 Problems 69
Chapter 9 Electrochemistry 70
91 Oxidation-Reduction Reactions 70
92 Voltaic Cells 71
93 Electrode Potentials and Cell Potentials 73
94 The Uses of Electrode Potentials 77 Problems 79
Chapter 10 Atomic Structure and Periodicity 81
101 The Atomic Spectrum of Hydrogen and the Bohr Theory81
102 The Properties of Microscopic Particles 82
103 The Structure of Hydrogen Atom 83
104 Many-Electron Atoms 88
The Periodic Table 91 Problems 93
105
Chapter 11 Covalent Bond and Intermolecular Forces 95
111 Covalent Bond and the Valence Bond Theory 95
112 Hybrid Orbital Theory 98
113 Molecular Orbital Theory 101
Delocalized π Bond 104
114
115 Intermolecular Forces and Hydrogen Bonding 105 Problems 107
Chapter 12 Coordination Compounds 109
121 Introduction to Coord ination Compounds 109
122 Bonding Theory of Coordination Compounds 112
123 Coordination Equilibria 114
Chelate 117
124
Problems 118
Chapter 13 Colloids 119
131 Colloidal Disperse System 119
132 The Properties of Sol 119
Problems 124
Keys to Exercises 125
Appendix A Standard Thermodynamic Data for Selected Substances at 29815 K 131 Appendix B Standard Molar Enthalpies of Combustion for Selected Substances at 29815 K 133 Appendix C Cumulative Stability Constants of Coordination Compounds
(29815 K) 134 References 140
