常用农药液相色谱-四极杆-飞行时间质谱图集及裂解规律

1.本书系统研究了电喷雾电离下常用农药的质谱裂解规律，补充了对于农药的质谱裂解规律尤其是电喷雾电离下偶电子离子的裂解规律研究方面的空白。本书结合高分辨质谱和线性离子阱三级扫描，推测给出了每个农药的裂解规律。 2.本书给出了详细的源内裂解信息，提供了部分易裂解农药源内裂解碎片的完整色谱和质谱信息，可作为辅助手段避免假阳性和假阴性。 3.质谱信息全面，本书提供了提取流色谱图、同位素丰度比质谱图和6个碰撞能量下的高分辨二级谱图，谱图信息全面。 4.农药种类具有代表性，本书涉及的农药绝大部分是GB 2763—2019中包含的农药品种，为我国登记的常用品种，因此具有较强的代表性和实用性。

本书包括388种常用农药及其代谢物的中英文名称、CAS登记号、分子式、分子量、离子加合方式等基础信息，以及农药母体及典型源内裂解碎片的提取离子流色谱图、分子离子峰同位素分布图、不同碰撞能下的二级高分辨谱图，在此基础上给出了每个农药的推测质谱裂解规律图。本书涉及的农药及其代谢物品种较全且具有较强的代表性，可供科研单位、高等院校、质检机构、第三方检测机构等各类从事农药化学污染物质谱分析计算研究与应用等工作的检测技术人员、科研人员参考使用。

贺泽英，农业农村部环境保护科研监测所，副研究员，毕业于中国农业大学农药学专业，一直从事农药残留分析研究工作。开发了多种基于色谱-串联质谱的农药残留快速和高通量分析方法，参与制定农药残留检测方法国家标准多项，部分研究成果发表在《Journal of Agricultural and food Chemistry》、《Food Chemistry》、《Journal of Chromatography A》《Analityical and Bioanalytical Chemistry》等国际期刊上，对于质谱分析具有较好的研究基础。

Abamectin阿维菌素/002
Acephate乙酰甲胺磷/004
Acetamiprid啶虫脒/006
Acetochlor乙草胺/008
Acetochlor in-source fragment 224 乙草胺源内裂解碎片224/010
Acifluorfen三氟羧草醚/012
Alachlor甲草胺/014
Alachlor in-source fragment 238 甲草胺源内裂解碎片238/016
Albendazole丙硫多菌灵/018
Aldicarb涕灭威/020
Aldicarb in-source fragment 116 涕灭威源内裂解碎片116/022
Aldicarb sulfone涕灭威砜/024
Aldicarb sulfoxide涕灭威亚砜/026
Ametoctradin唑嘧菌胺/028
Ametryn莠灭净/030
Amidosulfuron酰嘧磺隆/032
Amisulbrom吲唑磺菌胺/034
Anilazine敌菌灵/036
Anilofos莎稗磷/038
Atrazine莠去津/040
Azinphos-methyl保棉磷/042
Azinphos-methyl in-source fragment 132 保棉磷源内裂解碎片132/044
Azinphos-methyl in-source fragment 160 保棉磷源内裂解碎片160/046
Azoxystrobin嘧菌酯/048
Benalaxyl苯霜灵/050
Benazolin草除灵/052
Bendiocarb恶虫威/054
Benfuracarb丙硫克百威/056
Benfuracarb in-source fragment 190 丙硫克百威源内裂解碎片190/058
Benomyl苯菌灵/060
Bensulfuron-methyl苄嘧磺隆/062
Bentazone灭草松/064
Benziothiazolinone噻霉酮/066
Benzovindiflupyr苯并烯氟菌唑/068
Benzoximate苯螨特/070
Benzoximate in-source fragment 199 苯螨特源内裂解碎片199/072
Bifenazate联苯肼酯/074
Bifenazate in-source fragment 198 联苯肼酯源内裂解碎片 198/076
Bifenox甲羧除草醚/078
Bifenthrin联苯菊酯/080
Bioresmethrin生物苄呋菊酯/082
Bispyribac-sodium双草醚/084
Bitertanol联苯三唑醇/086
Boscalid啶酰菌胺/088
Bromuconazole糠菌唑/090
Bupirimate乙嘧酚磺酸酯/092
Buprofezin噻嗪酮/094
Butachlor丁草胺/096
Butachlor in-source fragment 238 丁草胺源内裂解碎片 238/098
Butralin仲丁灵/100
Cadusafos硫线磷/102
Carbaryl甲萘威/104
Carbaryl in-source fragment 145 甲萘威源内裂解碎片145/106
Carbendazim多菌灵/108
Carbofuran克百威/110
Carbofuran-3-hydroxy3-羟基克百威/112
Carbofuran-3-hydroxy in-3-source fragment 163 羟基克百威源内裂解碎片163/114
Carbofuran-3-hydroxy in-3-source fragment 220 羟基克百威源内裂解碎片220/116
Carbosulfan丁硫克百威/118
Carboxin萎锈灵/120
Carfentrazone-ethyl唑草酮/122
Chlorantraniliprole氯虫苯甲酰胺/124
Chlorbenzuron灭幼脲/126
Chlordimeform杀虫脒/128
Chlorfenvinphos毒虫畏/130
Chlorfluazuron氟啶脲/132
Chloridazon杀草敏/134
Chlorimuron-ethyl氯嘧磺隆/136
Chlorpropham氯苯胺灵/138
Chlorpropham  in-source fragment 172 氯苯胺灵源内裂解碎片172/140
Chlorpyrifos毒死蜱/142
Chlorpyrifos-methyl甲基毒死蜱/144
Chlorsulfuron氯磺隆/146
Chlortoluron绿麦隆/148
Chromafenozide环虫酰肼/150
Cinosulfuron醚磺隆/152
Clethodim烯草酮/154
Clethodim sulfone烯草酮砜/156
Clethodim sulfoxide烯草酮亚砜/158
Clofentezine四螨嗪/160
Clomazone异吖恶草酮/162
Clothianidin噻虫胺/164
Coumaphos蝇毒磷/166
Coumoxystrobin丁香菌酯/168
Cyanazine氰草津/170
Cyantraniliprole溴氰虫酰胺/172
Cyazofamid氰霜唑/174
Cyclosulfamuron环丙嘧磺隆/176
Cycloxydim噻草酮/178
Cyflufenamid环氟菌胺/180
Cyflumetofen丁氟螨酯/182
Cyhalothrin氯氟氰菊酯/184
Cymoxanil霜脲氰/186
Cymoxanil in-source fragment 128 霜脲氰源内裂解碎片128/188
Cyproconazole环丙唑醇/190
Cyprodinil嘧菌环胺/192
Cyromazine灭蝇胺/194
Dazomet棉隆/196
Deltamethrin溴氰菊酯/198
Demeton内吸磷/200
Demeton-S-methyl sulfone甲基砜内吸磷/202
Demeton-S-sulfone内吸磷-S-砜/204
Demeton-S-sulfoxide内吸磷-S-亚砜/206
Diafenthiuron丁醚脲/208
Diazinon二嗪磷/210
Dichlofluanid苯氟磺胺/212
Dichlorvos敌敌畏/214
Diclobutrazol苄氯三唑醇/216
Diclofop-methyl禾草灵/218
Dicrotophos百治磷/220
Diethofencarb乙霉威/222
Diethyl aminoethyl hexanoate胺鲜酯/224
Difenoconazole苯醚甲环唑/226
Diflubenzuron除虫脲/228
Diflufenican吡氟酰草胺/230
Dimepiperate哌草丹/232
Dimethenamid二甲吩草胺/234
Dimethenamid in-source fragment 244 二甲吩草胺源内裂解碎片244/236
Dimethoate乐果/238
Dimethoate in-source fragment 199 乐果源内裂解碎片199/240
Dimethomorph烯酰吗啉/242
Dimoxystrobin醚菌胺/244
Diniconazole烯唑醇/246
Dinotefuran呋虫胺/248
Diphenylamine二苯胺/250
Disulfoton乙拌磷/252
Disulfoton sulfone乙拌磷砜/254
Disulfoton sulfoxide乙拌磷亚砜/256
Diuron敌草隆/258
Edifenphos敌瘟磷/260
Emamectin甲氨基阿维菌素/262
Enestroburin烯肟菌酯/264
EPN苯硫磷/266
Epoxiconazole氟环唑/268
Ethion乙硫磷/270
Ethion in-sourcefragment 199 乙硫磷源内裂解碎片199/272
Ethiprole乙虫腈/274
Ethirimol乙嘧酚/276
Ethofumesate乙氧呋草黄/278
Ethoprophos灭线磷/280
Ethoxyquin乙氧喹啉/282
Ethoxysulfuron乙氧磺隆/284
Etofenprox醚菊酯/286
Etoxazole乙螨唑/288
Etrimfos乙嘧硫磷/290
Famoxadone吖恶唑菌酮/292
Fenamidone咪唑菌酮/294
Fenaminstrobin烯肟菌胺/296
Fenamiphos苯线磷/298
Fenamiphos sulfone苯线磷砜/300
Fenamiphos sulfoxide苯线磷亚砜/302
Fenarimol氯苯嘧啶醇/304
Fenazaquin喹螨醚/306
Fenbuconazole腈苯唑/308
Fenhexamid环酰菌胺/310
Fenitrothion杀螟硫磷/312
Fenobucarb仲丁威/314
Fenothiocarb苯硫威/316
Fenoxanil稻瘟酰胺/318
Fenoxaprop-ethyl吖恶唑禾草灵/320
Fenoxycarb苯氧威/322
Fenpropathrin甲氰菊酯/324
Fenpropidin苯锈啶/326
Fenpropimorph丁苯吗啉/328
Fenpyrazamine胺苯吡菌酮/330
Fenpyroximate唑螨酯/332
Fensulfothion丰索磷/334
Fensulfothion oxon氧丰索磷/336
Fensulfothion oxon sulfone 氧丰索磷砜/338
Fensulfothion sulfone丰索磷砜/340
Fenvalerate氰戊菊酯/342
Fipronil氟虫腈/344
Fipronil desulfinyl氟甲腈/346
Fipronil sulfide氟虫腈硫化物/348
Fipronil sulfone氟虫腈砜/350
Flonicamid氟啶虫酰胺/352
Florasulam双氟磺草胺/354
Fluazifop-butyl吡氟禾草灵/356
Fluazinam氟啶胺/358
Flubendiamide氟苯虫酰胺/360
Flucarbazone-sodium氟唑磺隆/362
Flucetosulfuron氟吡磺隆/364
Flucythrinate氟氰戊菊酯/366
Flufenacet氟噻草胺/368
Flufenoxuron氟虫脲/370
Flumetralin氟节胺/372
Flumetsulam唑嘧磺草胺/374
Flumorph氟吗啉/376
Fluopicolide氟吡菌胺/378
Fluopyram氟吡菌酰胺/380
Fluoroglycofen-ethyl乙羧氟草醚/382
Flurtamone呋草酮/384
Flusilazole氟硅唑/386
Fluthiacet-methyl嗪草酸甲酯/388
Flutolanil氟酰胺/390
Flutriafol粉唑醇/392
Fluxapyroxad氟唑菌酰胺/394
Fomesafen氟磺胺草醚/396
Fonofos地虫硫磷/398
Forchlorfenuron氯吡脲/400
Formothion安硫磷/402
Fosthiazate噻唑磷/404
Fosthiazate in-source fragment 228 噻唑磷源内裂解碎片228/406
Furathiocarb呋线威/408
Halosulfuron-methyl氯吡嘧磺隆/410
Heptenophos庚烯磷/412
Hexaconazole己唑醇/414
Hexaflumuron氟铃脲/416
Hexazinone环嗪酮/418
Hexythiazox噻螨酮/420
Imazalil抑霉唑/422
Imazamox甲氧咪草烟/424
Imazapic甲咪唑烟酸/426
Imazethapyr咪唑乙烟酸/428
Imibenconazole亚胺唑/430
Imidacloprid吡虫啉/432
Imidaclothiz氯噻啉/434
Indoxacarb茚虫威/436
Iodosulfuron-methyl-sodium甲基碘磺隆钠盐/438
Ipconazole种菌唑/440
Iprobenfos异稻瘟净/442
Iprodione异菌脲/444
Iprovalicarb缬霉威/446
Isazofos氯唑磷/448
Isocarbophos水胺硫磷/450
Isocarbophos in-source fragment 231 水胺硫磷源内裂解碎片231/452
Isocarbophos in-source fragment 273 水胺硫磷源内裂解碎片273/454
Isofenphos-methyl甲基异柳磷/456
Isofenphos-methyl in-source fragment 231 甲基异柳磷源内裂解碎片231/458
Isofenphos-methyl in-source fragment 273 甲基异柳磷源内裂解碎片 273/460
Isoprocarb异丙威/462
Isoprothiolane稻瘟灵/464
Isoproturon异丙隆/466
Isopyrazam吡唑萘菌胺/468
Ivermectin依维菌素/470
Kresoxim-methyl醚菌酯/472
Lactofen乳氟禾草灵/474
Linuron利谷隆/476
Lufenuron虱螨脲/478
Malaoxon马拉氧磷/480
Malathion马拉硫磷/482
Mandipropamid双炔酰菌胺/484
Mefenacet苯噻酰草胺/486
Mepronil灭锈胺/488
Mesosulfuron-methyl甲基二磺隆/490
Metaflumizone氰氟虫腙/492
Metalaxyl甲霜灵/494
Metamifop吖恶唑酰草胺/496
Metamitron苯嗪草酮/498
Metazachlor吡唑草胺/500
Metazosulfuron嗪吡嘧磺隆/502
Metconazole叶菌唑/504
Methacrifos虫螨畏/506
Methacrifos in-source fragment 209 虫螨畏源内裂解碎片209/508
Methamidophos甲胺磷/510
Methidathion杀扑磷/512
Methiocarb甲硫威/514
Methiocarb in-source fragment 169 甲硫威源内裂解碎片169/516
Methiocarb sulfone甲硫威砜/518
Methiocarb sulfoxide甲硫威亚砜/520
Methiocarb sulfoxide in-source fragment 185 甲硫威亚砜源内裂解碎片185/522
Methomyl灭多威/524
Methoxyfenozide甲氧虫酰肼/526
Methoxyfenozide in-source fragment 313 甲氧虫酰肼源内裂解碎片313/528
Metolachlor异丙甲草胺/530
Metolcarb速灭威/532
Metolcarb in-source fragment 109 速灭威源内裂解碎片109/534
Metrafenone苯菌酮/536
Metribuzin嗪草酮/538
Metsulfuron-methyl甲磺隆/540
Mevinphos速灭磷/542
Mevinphos in-source fragment 193 速灭磷源内裂解碎片193/544
Molinate禾草敌/546
Monocrotophos久效磷/548
Monocrotophos in-source fragment 193 久效磷源内裂解碎片193/550
Monosulfuron单嘧磺隆/552
Myclobutanil腈菌唑/554
Napropamide敌草胺/556
Nicosulfuron烟嘧磺隆/558
Nitenpyram烯啶虫胺/560
Novaluron氟酰脲/562
Omethoate氧乐果/564
Orthosulfamuron嘧苯胺磺隆/566
Oxadiargyl丙炔吖恶草酮/568
Oxadiazon吖恶草酮/570
Oxamyl杀线威/572
Oxamyl oxime杀线威肟/574
Oxaziclomefone吖恶嗪草酮/576
Oxydemeton-methyl亚砜磷/578
Paclobutrazol多效唑/580
Parathion对硫磷/582
Parathion-methyl甲基对硫磷/584
Penconazole戊菌唑/586
Pencycuron戊菌隆/588
Pendimethalin二甲戊灵/590
Pendimethalin in-source fragment 212 二甲戊灵源内裂解碎片212/592
Penflufen氟唑菌苯胺/594
Penoxsulam五氟磺草胺/596
Penthiopyrad吡噻菌胺/598
Permethrin氯菊酯/600
Phenamacril氰烯菌酯/602
Phenmedipham甜菜宁/604
Phenthoate稻丰散/606
Phorate甲拌磷/608
Phorate sulfone甲拌磷砜/610
Phorate sulfoxide甲拌磷亚砜/612
Phosalone伏杀硫磷/614
Phosfolan硫环磷/616
Phosfolan-methyl甲基硫环磷/618
Phosmet亚胺硫磷/620
Phosmet oxon氧亚胺硫磷/622
Phosphamidon磷胺/624
Phoxim辛硫磷/626
Picolinafen氟吡酰草胺/628
Picoxystrobin啶氧菌酯/630
Pinoxaden唑啉草酯/632
Piperonyl butoxide增效醚/634
Piperonyl butoxide in-source fragment 177 增效醚源内裂解碎片177/636
Pirimicarb抗蚜威/638
Pirimicarb-desmethyl脱甲基抗蚜威/640
Pirimiphos-methyl甲基嘧啶磷/642
Pretilachlor丙草胺/644
Procymidone腐霉利/646
Profenofos丙溴磷/648
Promecarb猛杀威/650
Prometryn扑草净/652
Propachlor毒草胺/654
Propamocarb霜霉威/656
Propanil敌稗/658
Propaquizafop喔草酯/660
Propargite 炔螨特/662
Propargite in-source fragment 231 炔螨特源内裂解碎片231/664
Propiconazole丙环唑/666
Propisochlor异丙草胺/668
Propoxur残杀威/670
Propoxur in-source fragment 168 残杀威源内裂解碎片168/672
Propyrisulfuron丙嗪嘧磺隆/674
Propyzamide炔苯酰草胺/676
Proquinazid丙氧喹啉/678
Prosulfocarb苄草丹/680
Prothioconazole丙硫菌唑/682
Pymetrozine吡蚜酮/684
Pyraclostrobin吡唑醚菌酯/686
Pyrametostrobin唑胺菌酯/688
Pyraoxystrobin唑菌酯/690
Pyrazosulfuron-ethyl吡嘧磺隆/692
PyrethrinsⅠ除虫菊素Ⅰ/694
Pyrethrins Ⅱ除虫菊素Ⅱ/696
Pyribenzoxim嘧啶肟草醚/698
Pyridaben哒螨灵/700
Pyridalyl三氟甲吡醚/702
Pyridaphenthion哒嗪硫磷/704
Pyrimethanil嘧霉胺/706
Pyrimorph丁吡吗啉/708
Pyriproxyfen吡丙醚/710
Pyrisoxazole啶菌吖恶唑/712
Quinalphos喹硫磷/714
Quizalofop-ethyl喹禾灵/716
Rimsulfuron砜嘧磺隆/718
Rotenone鱼藤酮/720
Saflufenacil苯嘧磺草胺/722
Sedaxane氟唑环菌胺/724
Sethoxydim烯禾啶/726
Silthiofame硅噻菌胺/728
Simazine西玛津/730
Simetryn西草净/732
Spinetoram J乙基多杀菌素J/734
Spinetoram L乙基多杀菌素L/736
Spinosad A多杀霉素A/738
Spinosad D多杀霉素D/740
Spirodiclofen螺螨酯/742
Spiromesifen螺甲螨酯/744
Spiromesifen in-source fragment 273 螺甲螨酯源内裂解碎片273/746
Spirotetramat螺虫乙酯/748
Spirotetramat-enol螺虫乙酯-烯醇/750
Spirotetramat-enol-glucoside螺虫乙酯-烯醇-葡萄糖苷/752
Spirotetramat-keto-hydroxy螺虫乙酯-酮基-羟基/754
Spirotetramat-mono-hydroxy螺虫乙酯-单-羟基/756
Sulcotrione磺草酮/758
Sulfotep治螟磷/760
Sulfoxaflor 氟啶虫胺腈/762
tau-fluvalinate氟胺氰菊酯/764
Tebuconazole戊唑醇/766
Tebufenozide虫酰肼/768
Tebufenozide in-source fragment 297 虫酰肼源内裂解碎片297/770
Tebuthiuron丁噻隆/772
Teflubenzuron氟苯脲/774
Terbufos特丁硫磷/776
Terbufos in-source fragment 233 特丁硫磷源内裂解碎片233/778
Terbufos sulfone特丁硫磷砜/780
Terbufos sulfoxide特丁硫磷亚砜/782
Terbufos sulfoxide in-source fragment 187 特丁硫磷亚砜源内裂解碎片187/784
Terbuthylazine特丁津/786
Tetraconazole四氟醚唑/788
Thiabendazole噻菌灵/790
Thiacloprid噻虫啉/792
Thiamethoxam噻虫嗪/794
Thiamethoxam in-source fragment 211 噻虫嗪源内裂解碎片211/796
Thidiazuron噻苯隆/798
Thiencarbazone-methyl噻酮磺隆/800
Thifensulfuron-methyl噻吩磺隆/802
Thifluzamide噻氟菌胺/804
Thiodicarb硫双威/806
Thiophanate-methyl甲基硫菌灵/808
Tolclofos-methyl甲基立枯磷/810
Tolfenpyrad唑虫酰胺/812
Tolylfluanid甲苯氟磺胺/814
Tolylfluanid in-source fragment 238 甲苯氟磺胺源内裂解碎片238/816
Topramezone苯唑草酮/818
Tralkoxydim三甲苯草酮/820
Triadimefon三唑酮/822
Triallate野麦畏/824
Triasulfuron醚苯磺隆/826
Triazophos三唑磷/828
Tribenuron-methyl苯磺隆/830
Trichlorfon敌百虫/832
Triclopyricarb氯啶菌酯/834
Tricyclazole三环唑/836
Trifloxystrobin肟菌酯/838
Triflumizole氟菌唑/840
Triflumuron杀铃脲/842
Triflusulfuron-methyl氟胺磺隆/844
Triticonazole灭菌唑/846
Tritosulfuron三氟甲磺隆/848
Uniconazole烯效唑/850
Vamidothion蚜灭磷/852
Zoxamide苯酰菌胺/854
参考文献/856
化合物中文名称索引/857
CAS登录号索引/862