Introduction
0.1 Physical chemistry
0.1.1 Contents of physical chemistry
0.1.2 Issues to be solved by physical chemistry
0.1.3 Advice for studying physical chemistry
0.2 Indication and operation of physical quantity
0.2.1 Indication of physical quantity
0.2.2 Operation of physical quantity
Chapter 1 The pVT properties of gases
1.1 State equation of the perfect gas
1.1.1 Empirical law of gas
1.1.2 State equation of the perfect gas
1.1.3 Model of the perfect gas
1.2 Mixture of the perfect gas
1.2.1 Composition of perfect gas mixture
1.2.2 Dalton' s law of partial pressures
1.2.3 Amagat' s law of partial volumes
1.2.4 Mean molar mass of mixed gas
1.3 Liquefaction of real gas and critical properties
1.3.1 Saturated vapor pressure of liquid
1.3.2 Liquefaction of real gas and critical properties
1.4 State equations of real gas
1.4.1 The van der Waals equation
1.4.2 The virial equation of state
1.5 The law of corresponding states
1.5.1 Compression factors
1.5.2 The law of corresponding states
EXERCISES
Chapter 2 The first law of thermodynamics
2.1 The basic concept of thermodynamics
2.1.1 System and surroundings
2.1.2 Extensive property and intensive property of system
2.1.3 State and state function of system
2.1.4 Equilibrium state of thermodynamics
2.1.5 Process and path
2.2 The first law of thermodynamics
2.2.1 Heat
2.2.2 Work
2.2.3 Calculation of volume work
2.2.4 Thermodynamic energy
2.2.5 The first law of thermodynamics
2.3 The heat at constant volume, the heat at constant pressure and enthalpy
2.3.1 The heat at constant volume
2.3.2 The heat at constant pressure
2.3.3 Enthalpy
2.3.4 Hess's Law
2.4 Heat capacity
2.4.1 Heat capacity
2.4.2 Relation between Cp,m and p
2.4.3 Empirical formula between Cp,m and T
2.4.4 Relation between Cp,m and Cv,m
2.4.5 Joule experiment
2.5 Reversible process and equation of adiabatic reversible process of the perfect gas
2.5.1 Reversible process
2.5.2 Isothermal reversible process of the perfect gas
2.5.3 Adiabatic reversible process of the perfect gas
2.6 Phase transformation process
2.6.1 Phase and enthalpy of phase transition
2.6.2 Calculation of AH of phase transformation process
2.7 Standard molar enthalpy of reaction
2.7.1 Chemical stoichiometric number
2.7.2 Extent of a reaction
2.7.3 Molar enthalpy of reaction
2.7.4 Standard molar enthalpy of reaction
2.8 Standard molar enthalpy of formation and standard molar enthalpy of combustion
2.8.1 Standard molar enthalpy of formation
2.8.2 Standard molar enthalpy of combustion
2.8.3 The temperature - dependence of ArHm (T) -- Kirchhoff's formula
2.8.4 The relation between Qp and Qv
2.8.5 Maximum temperature of explosion and flame reaction
2.9 Throttling process and Joule - Thomson effect
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2.9.1 Joule -Thomson experiment
Chapter 3 The second law of thermodynamics
Chapter 4 The thermodynamics of multi-component systems
Chapter 5 Chemical equilibrium
Chapter 6 Phase equilibrium
Chapter 7 Electrolyte solution
Chapter 8 Electrochemical system
Chapter 9 Interface phenomena
Chapter 10 Chemical kinetics
EXERCISES
REFERENCE BOOKS
