Introduction
0.1 Physical chemistry
0.1.1 Contents of physical chemistry
0.1.2 Issues to be solved by physical chemistry
0.1.3 Advice for studying physical chemistry
0.2 Indication and operation of physical quantity
0.2.1 Indication of physical quantity
0.2.2 Operation of physical quantity
Chapter 1 The pVT properties of gases
1.1 State equation of the perfect gas
1.1.1 Empirical law of gas
1.1.2 State equation of the perfect gas
1.1.3 Model of the perfect gas
1.2 Mixture of the perfect gas
1.2.1 Composition of perfect gas mixture
1.2.2 Dalton’S law of partial pressures
1.2.3 Amagat’S law of partial volumes
1.2.4 Mean molar mass of mixed gas
1.3 Liquefaction of real gas and critical properties
1.3.1 Saturated vapor pressure of liquid
1.3.2 Liquefaction of real gas and critical properties
1.4 State equations of real gas
1.4.1 The van der Waals equation
1.4.2 The virial equation of state
1.5 The law of corresponding states
1.5.1 Compression factors
1.5.2 The law of corresponding states。
EXERCISES
Chapter 2 The first law of thermodynamics
2.1 The basic concept of thermodynamics
2.1.1 System and surroundings
2.1.2 Extensive property and intensive property of system
2.1.3 State and state function of system
2.1.4 Equilibrium state of thermodynamics
2.1.5 Process and path
2.2 The first law of thermodynamics
2.2.1 Heat
2.2.2 Work
2.2.3 Calculation of volume work
2.2.4 Thermodynamic energy
2.2.5 The first law of thermodynamics.
2.3 The heat at constant volume.the heat at constant pressure and enthalpy
2.3.1 The heat at constant volume
2.3.2 The heat at constant pressure
2.3.3 Enthalpy.
2.3.4 Hess’s Law
2.4 Heat capacity
2.4.1 Heat capacity
2.4.2 Relation between Cp,mand P
2.4.3 Empirical formula between Cp,m and T
